Unexpected Side Reaction in the Intermolecular N-H Insertion of Phenyl Diazoacetates with Arylamines

Unexpected side reaction is discovered from the N-H insertion of phenyl diazoacetates with arylamines in the presence of Rh2(OAc)4 catalyst. This side reaction is not evident with copper catalysts such as Cu(acac)2 or Cu(OTf)2. Good yieldof the N-H insertion was obtained by using 0.2% of copper catalyst.

作 者： Yan Xin ZHU Yuan Hua WANG Zhi Yong CHEN Wen Hao HU   作者單位： Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041  刊 名： 中國化學(xué)快報（英文版）  ISTIC SCI 英文刊名： CHINESE CHEMICAL LETTERS  年，卷(期)： 2005 16(3)  分類號：   關(guān)鍵詞： N-H insertion   diazoester   carbene   ylide   rearrangement  

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